Gas Phase Synthesis of Multifunctional Fe-Based Nanocubes

Jerome Vernieres, Stephan Steinhauer, Junlei Zhao, Audrey Chapelle, Philippe Menini, Nicolas Dufour, Rosa E. Diaz, Kai Nordlund, Flyura Djurabekova, Panagiotis Grammatikopoulos, and Mukhles Sowwan*, 2017
Fusion TEM holder tip
Image courtesy of Advanced Functional Materials

Abstract

Magnetron-sputtering inert-gas condensation is an emerging technique offering single-step, chemical-free synthesis of nanoparticles with well-defined morphologies optimized for specific applications. In this study, the authors report a flexible approach to produce Fe nanocubes as building blocks for high-performance NO2 gas sensor devices, and hybrid FeAu nanocubes with magneto-plasmonic properties. Considering that nucleation happens within a short distance from the sputtering target, the authors utilize the high-permeability and resultant screening effect induced by magnetic Fe targets of various thicknesses to manipulate the magnetic field configuration and plasma confinement. The authors thus readily switch from bimodal to single-Gaussian size distributions of Fe nanocubes by modifying their primordial thermal environments, as explained by a combination of modeling methods. Simultaneously, the authors obtain a material yield increase of more than one order of magnitude compared to experiments using postgrowth mass filtration. The effectiveness of the method is demonstrated by the deposition of Fe nanocubes on microhotplate devices, leading to unprecedented NO2 detection performance for Fe-based chemoresistive gas sensors. The exceedingly low detection limit down to 3 ppb is attributed to a morphological change in operando from Fe/Fe-oxide core/shell to specific hollow-nanocube structures, as revealed by in situ environmental transmission electron microscopy.

Impact Statement

Sensing properties of Fe-based nanostrcutures was investigated inside an ETEM through structural and morphological changes.